ASTM D6093-97(2022)

4.1?This test method measures the volume of dry coating obtainable from a given volume of liquid coating. This value is useful for calculating the volatile organic content (VOC) of a coating and could be used to estimate the coverage (square feet of surface covered at a specified dry film thickness per unit volume) obtainable with different coating products.

4.2?For various reasons the volume nonvolatile value obtained for a coating is often not equal to that predicted from simple linear addition of the weights and volumes of the raw materials in a formulation. One reason is that the volume occupied by a solution of resin in solvent may be the same, greater, or less than the total volume of the separate ingredients. Such contraction or expansion of resin solutions is governed by a number of factors, one of which is the extent and direction of spread between solubility parameters of the resin and solvent.

4.3?The spatial configuration of the pigment particles and the degree to which the pigment particles are filled with the binder also affect the volume of a dry coating film. Above the critical pigment volume concentration, the apparent volume of the dry film is significantly greater than theoretical due to the increase in unfilled voids between pigment particles. The use of volume nonvolatile matter values in such instances should be carefully considered as the increased volume is largely due to air trapped in these voids.

4.4?For thin films, the issue of critical pigment volume effects is usually not a concern. With high poly(vinyl chloride) (PVC) films, however, liquid displacement of air voids takes place with difficulty even under high pressures. Helium solves this problem since, as a gas, it readily penetrates and displaces air, water, and volatile solvents even at low pressures. Purging the gas pycnometer flushes these materials from the film.

1.1?This test method covers the determination of the percent volume nonvolatile matter of a variety of clear and pigmented coatings. The approach used should provide faster and more accurate results than the use of the liquid displacement technique in Test Method D2697, particularly for coatings that are difficult to wet or that contain voids, cracks or other defects. The improvement in accuracy stems from the superior ability of helium gas under pressure to penetrate very small pores and surface irregularities in dried films. This provides a more accurate determination of void volumes than can be obtained via liquid displacement.

1.2?The technique will provide results under the following constraints:

1.3?The values stated in inch-pound units are to be regarded as standard. The values given in parentheses are mathematical conversions to SI units that are provided for information only and are not considered standard.

1.4?This standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility of the user of this standard to establish appropriate safety, health, and environmental practices and determine the applicability of regulatory limitations prior to use.

1.5?This international standard was developed in accordance with internationally recognized principles on standardization established in the Decision on Principles for the Development of International Standards, Guides and Recommendations issued by the World Trade Organization Technical Barriers to Trade (TBT) Committee.